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|Title:||Application of the extended real associated solution theory to excess molar enthalpies and excess molar volumes of binary mixtures of (benzene or 1-alkanol + quinoline)||Authors:||Deenadayalu, Nirmala
Letcher, Trevor M.
|Keywords:||Excess molar enthalpy;Excess molar volume;Alkanols;ERAS||Issue Date:||1-Jun-2005||Publisher:||Elsevier||Source:||Deenadayalu, Nirmala and Letcher, T. M. Application of the extended real associated solution theory to excess molar enthalpies and excess molar volumes of binary mixtures of (benzene or 1-alkanol + quinoline).' 'Journal of Molecular Liquids. 121,2-3 (2005): 143-147||Abstract:||Excess molar enthalpies and excess molar volumes of binary mixtures of (benzene or methanol or ethanol or 1-propanol or 1- butanol+quinoline) as a function of composition at a pressure of 1 atm and a temperature of 298.15 K have been used to test the Extended Real Solution Theory, ERAS, of nonelectrolyte solutions. The ERAS theory accounts for free volume effects according to the Flory–Patterson theory and for association effects: self and crossassociation between the molecules involved. The ERAS theory results for the binary mixtures (benzene or an alkanol+quinoline) indicates strong hydrogen bonding effects between unlike molecules given by the predicted hydrogen bonding energy between two dissimilar compounds. Comparison is also made between the chemical and physical contribution to the ERAS theory. The Extended Real Associated Solution theory describes the published Vm E data better than the published Hm E data.||URI:||http://hdl.handle.net/10321/850||Rights:||The electronic version of the article published in Journal of Molecular Liquids 2005, 121(2-3): 143-147 © 2005 copyright Elsevier. Journal of Molecular Liquids is available online at: http://www.sciencedirect.com/science/article/pii/S0167732205000310|
|Appears in Collections:||Research Publications (Applied Sciences)|
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