Please use this identifier to cite or link to this item: http://hdl.handle.net/10321/3011
Title: Cobalt boron nitride : a novel heterogeneous catalyst for the synthesis of medicinally important α-amino quinoline phosphonates
Authors: Sureshkumar, M 
Anand, Krishnan 
Muthu, T. 
Gengan, Robert Moonsamy 
Keywords: 2-Methoxy 3-formyl quinoline;Diethyl phosphite;Boron nitride;Cobalt;Heterogeneous catalyst
Issue Date: 2016
Publisher: Taylor and Fancis
Source: Sureshkumar, M. et al. 2016. Cobalt boron nitride : a novel heterogeneous catalyst for the synthesis of medicinally important α-amino quinoline phosphonates. Phosphorus, Sulfur, and Silicon and the Related Elements. 191(7): 1022-1029.
Abstract: A novel cobalt supported on boron nitride (CoBNT) heterogeneous catalyst for the synthesis of α-amino quinoline phosphonates (AQPs) is reported in the present work. The CoBNT was synthesised by simply mix-ing boron nitride in a solution of cobalt acetate, under an inert atmosphere for 7 d followed by filtration; the yield was 94%. It exhibited excellent catalytic properties for the synthesis of 16 novel AQPs in a one pot mixture containing 2-methoxy 3-formyl quinoline, aniline derivatives and diethyl phosphite. Reactions were rapid, products were easily worked-up and were obtained in more than 90% yield. The CoBNT also exhibited higher catalytic activity than conventional catalysts and was re-used five times without significant decrease in catalytic activity.
URI: http://hdl.handle.net/10321/3011
ISSN: 1042-6507 (print)
1563-5325 (online)
Appears in Collections:Research Publications (Applied Sciences)

Show full item record

Page view(s)

62
checked on May 19, 2019

Google ScholarTM

Check


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.