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|Title:||Fabrication of copper nanoparticles decorated multiwalled carbon nanotubes as a high performance electrochemical sensor for the detection of neotame||Authors:||Bathinapatla, Ayyappa
Sabela, Myalowenkosi Innocent
|Keywords:||Neotame;Electrochemical sensor;Cyclic voltammetry;Differential pulse voltammetry||Issue Date:||2015||Publisher:||Elsevier||Source:||Bathinapatla, A;. Kanchi, S;. Singh, P;. Sabela, M. I. 2015. Fabrication of copper nanoparticles decorated multiwalled carbon nanotubes as a high performance electrochemical sensor for the detection of neotame. Biosensors and Bioelectronics Vol. 67 : 200–207||Journal:||Biosensors & bioelectronics ItemCrisRefDisplayStrategy.journals.deleted.icon||Abstract:||A highly sensitive and novel electrochemical sensor for the detection of neotame using differential pulse voltammetry with a modiﬁed glassy carbon electrode is presented. The method was further customized by the fabrication of the electrode surface with copper nanoparticles–ammonium piperidine dithiocar-bamate–mutiwalled carbon nanotubes assimilated with β-cyclodextrin. The multiwalled carbon nano-tubes assimilated with β-cyclodextrin/glassy carbon electrode exhibited catalytic activity towards the oxidation of neotame at a potential of 1.3 V at pH 3.0. The transmission electron microscopy, thermogravimetric analysis, frontier transform infrared spectroscopy and cyclic voltammetry were employed to characterize the electrochemical sensor. The sensitivity and detection limits of the electrode increased two-fold in contrast to the β-CD-MWCNTs/GCE sensor. The developed method was successfully applied for the determination of neotame in food samples, with results similar to those achieved by our modiﬁed capillary electrophoresis method with a 96% conﬁdence level.||URI:||http://hdl.handle.net/10321/1566||ISSN:||0956-5663|
|Appears in Collections:||Research Publications (Applied Sciences)|
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